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1.7
结语

能源、环境和实现资源高效利用的循环经济是当今社会发展的核心课题,高能电池将在发展电子信息、新能源及环境保护等面向21世纪的重大技术领域中具有举足轻重的地位和作用,固体电解质燃料电池有很多的优点,对人类现在的生活带来了许多便捷,有着很好的应用前景。

参考文献

[1]A.Radojkovic,Savic S M,Jovic N,et al.Structural and electrical properties of BaCe 0.9 Ee 0.1 O 2.95 electrolyte for IT-SOFCs[J].Electrochimica Acta,2015,161:153-158.

[2]Babu A S,Ranjit Bauri.Phase evolution and morphology of nanocrystalline BaCe 0.9 Er 0.1 O 3-δ protonconducting oxide synthesised by a novel modified solution combustion route[J].Journal of Physics and Chemistry of Solids,2015,87:80-86.

[3]Agnieszka Lacz,Katarzyna Grzesik,Pawe.Pasierb.Electrical properties of BaCeO 3 -based composite protonic conductors[J].Journal of Power Sources,2015,279:80-87.

[4]Yen-Chang Tsai,San-Yuan Chen,Jeng-Han Wang,et al.Chemical stability and electrical conductivity of BaCe 0.4 Zr 0.4 Gd 0.1 Dy 0.1 O 3-δ perovskite[J].Ceramics International 2015,41:10856-10860.

[5]Dimpul Konwar,Ngoc Thi Quynh Nguyen,Hyon Hee Yoon.Evaluation of BaZr 0.1 Ce 0.7 Y 0.2 O 3-δ electrolyteprepared by carbonate precipitation for a mixed ion-conducting SOFC [J].International Journal of Hydrogen Energy,2015,40:11651-11658.

[6]Medvedev D,Lyagaeva J,Plaksin S,et al.Sulfur and carbon tolerance of BaCeO 3 -BaZrO 3 proton-conducting materials[J].Journal of Power Sources,2015,273:716-723.

[7] Lagaeva J,Medvedev D,Demin A,et al.Insights on thermal and transport features of BaCe 0.8-x Zr x Y 0.2 O 3-δ proton-conducting materials[J].Journalof Power Sources,2015,278:436-444 .

[8]Feng Su,Changrong Xia,Ranran Peng.Novel fluoride-doped barium cerate applied as stable electrolyte in proton conducting solid oxide fuel cells[J].Journal of the European Ceramic Society,2015,35:3553-3558.

[9]Junfu Bu,Pär Göran Jönsson,Zhe Zhao.Dense and translucent BaZr x Ce 0.8-x Y 0.2 O 3-δ (x=0.5,0.6,0.7)proton conductors prepared by spark plasma sintering[J].Scripta Materialia,2015,107:145-148.

[10]P.Kim-Lohsoontorn,Paichitra C,Vorathamthongdee S.Low-temperature preparation of BaCeO 3 through ultrasonic-assisted precipitation for application in solid oxide electrolysis cell[J].Chemical Engineering Journal,2015,278:13-18.

[11] Cuijuan Zhang,Hailei Zhao,Nansheng Xu,et al.Influence of ZnO addition on the properties of high temperature proton conductor Ba 1.03 Ce 0.5 Zr 0.4 Y 0.1 O 3-δ synthesized via citrate -nitrate method[J].International Journal of Hydrogen Energy,2009,34:2739-2746.

[12] Bin Lin,Yingchao Dong,Songlin Wang,et al.Stable,easily sintered BaCe 0.5 Zr 0.3 Y 0.16 Zn 0.04 O 3-δ electrolyte-based proton-conducting solid oxide fuel cells by gel-casting and suspension spray[J].Journal of Alloys and Compounds,2009,478:590-593.

[13]Zhimin Zhong,Stability and conductivity study of the BaCe 0.9-x Zr x Y 0.1 O 2.95 systems [J].Solid State Ionics,2009,178:213-220.

[14]Noboru Taniguchi,Chiharu Nishimura,Junichi Kato.Endurance against moisture for protonic conductors of perovskite-type ceramics and preparation of practical conductors [J] .Solid State Ionics,2001,145:349-355.

[15]Wienstrijer S,H.D.Wiemhijfer.Investigation of the influence of zirconium substitution on the properties of neodymium-doped barium cerates[J].Solid State Ionics,1997,101-103:1113-1117.

[16]Abul K.Azad,John T.S.Irvine.High density and low temperature sintered proton conductor BaCe 0.5 Zr 0.35 Sc 0.1 Zn 0.05 O 3-δ [J].Solid State Ionics,2008,179:678-682.

[17]Kui Xie,Ruiqiang Yan,Xiaoxiang Xu,et al.A stable and thin BaCe 0.7 Nb 0.1 Gd 0.2 O 3-δ membrane prepared by simple all-solid-state process for SOFC[J].Journal of Power Sources,2009,187:403-406.

[18]Azad A K,J.T.S.Irvine.Synthesis,chemical stability and proton conductivity of the perovksites Ba(Ce,Zr) 1-x Sc x O 3-δ [J].Solid State Ionics,2007,178:635-640.

[19]Shangquan Zhang,Lei Bi,Lei Zhang,et al.Stable BaCe 0.5 Zr 0.3 Y 0.16 Zn 0.04 O 3-δ thin membrane prepared by in situ tape casting for proton-conducting solid oxide fuel cells[J].Journal of Power Sources,2009,188:343-346.

[20]Ruiqiang Yan,Qingfeng Wang,Guihua Chen,et al.A cubic BaCo 0.8 Nb 0.1 Fe 0.1 O 3-δ ceramic cathode for solid oxide fuel cell[J].Journal of Alloys and Compounds,2009,488:L35-L37.

[21]Ling Zhao,Beibei He,Zhiqin Xun,et al.Characterization and evaluation of NdBaCo 2 O 5+δ cathode for proton-conducting solid oxide fuel cells[J].International Journal of Hydrogen Energy 2010,35:753-756.

[22]Glockner R,Islam M S,Norby T.Protons and other defects in BaCeO 3 :a computational study[J].Solid State Ionics,1999,122:145-156.

[23]Jun Xu,Xiaoyong Lu,Yanzhi Ding,et al.Stable BaCe 0.5 Zr 0.3 Y 0.16 Zn 0.04 O 3-δ electrolyte-based proton-conducting solid oxide fuel cells with layered SmBa 0.5 Sr 0.5 Co 2 O 5+δ cathode [J].Journal of Alloys and Compounds,2009,488:208-210.

[24 ] Hanping Ding,Xingjian Xue.Novel layered perovskite GdBaCoFeO 5+δ as a potential cathode for proton-conducting solid oxide fuel cells[J].International Journal of Hydrogen Energy 2010,35:4311-4315.

[25]Bin Lin,Mingjun Hu,Jianjun Ma,et al.Stable,easily sintered BaCe 0.5 Zr 0.3 Y 0.16 Zn 0.04 O 3-δ electrolyte-based protonic ceramic membrane fuel cells with Ba 0.5 Sr 0.5 Zn 0.2 Fe 0.8 O 3-δ perovskite cathode[J].Journal of Power Sources,2008,183:479-484.

[26]Wen Xing,Paul Inge Dahl,Lasse Valland Roaas,Marie-Laure Fontaine,Yngve Larring,Partow P.Henriksen,Rune Bredesen.Hydrogen permeability of SrCe 0.7 Zr 0.25 Ln 0.05 O 3-δ membranes(Ln=Tm and Yb)[J].Journal of Membrane Science,2015,473:327-332.

[27]Shimada T,Wen C,Taniguchi N,et al.The high temperature proton conductor BaZr 0.4 Ce 0.4 In 0.2 O 3-α [J].Journal of Power Sources,2004,131:289-292.

[28]Youmin Guo,Ye Lin,Ran Ran,et al.Zirconium doping effect on the performance of proton-conducting BaZr y Ce 0.8-y Y 0.2 O 3-δ (0.0≤y≤0.8) for fuel cell applications [J] .Journal of Power Sources,2009,193:400-407.

[29]Nadja Zakowsky,Sylvia Williamson,John T.S.Irvine.Elaboration of CO 2 tolerance limits of BaCe 0.9 Y 0.1 O 3-δ electrolytes for fuel cells and other applications[J] .Solid State Ionics,2005,176:3019-3026.

[30]Wenping Sun,Zhen Shi,Shumin Fang,et al.A high performance BaZr 0.1 Ce 0.7 Y 0.2 O 3-δ -based solid oxide fuel cell with a cobalt-free Ba 0.5 Sr 0.5 FeO 3-δ Ce 0.8 Sm 0.2 O 2-δ composite cathode[J].International Journal of Hydrogen Energy 2009,35:7925-7929.

[31]Hanping Ding,Xingjian Xue.Proton conducting solid oxide fuel cells with layered PrBa 0.5 Sr 0.5 Co 2 O 5+δ perovskite cathode[J].International Journal of Hydrogen Energy 2010,35:2486-2490.

[32]Wenping Sun,Litao Yan,Bin Lin,et al.High performance proton-conducting solid oxide fuel cells with a stable Sm 0.5 Sr 0.5 Co 3-δ -Ce 0.8 Sm 0.2 O 2-δ composite cathode[J].Journal of Power Sources,2010,195:3155-3158.

[33]Hanping Ding,Xingjian Xue.A novel cobalt-free layered GdBaFe 2 O 5+δ cathode for proton conducting solid oxide fuel cells[J].Journal of Power Sources,2010,195:4139-4142.

[34]Lei Bi,Zetian Tao,Wenping Sun,et al.Proton-conducting solid oxide fuel cells prepared by a single step co-firing process[J].Journal of Power Sources,2009,191:428-432.

[35]Lei Bi,Shangquan Zhang,Shumin Fang,et al.A novel anode supported BaCe 0.7 Ta 0.1 Y 0.2 O 3-δ electrolyte membrane for proton-conducting solid oxide fuel cell[J].Electrochemistry Communications,2008,10:1598-1601.

[36]Yingxin Guo,Baoxin Liu,Qing Yang,et al.Preparation via microemulsion method and proton conduction at intermediate-temperature of BaCe 1-x Y x O 3-α [J].Electrochemistry Communications,2009,11:153-156.

[37]Cheng Chen,Guilin Ma.Proton conduction in BaCe 1-x Gd x O 3-α at intermediate temperature and its application to synthesis of ammonia at atmospheric pressure[J].Journal of Alloys and Compounds,2009,485:69-72.

[38]Guilin Ma,Hiroshige Matsumoto,Hiroyasu Iwahara.Ionic conduction and nonstoichiometry in non-doped Ba x CeO 3-α [J].Solid State Ionics,1999,122:237-247.

[39]Guilin Ma,Tetsuo Shimura,Hiroyasu Iwahara.Simultaneous doping with La 3+ and Y 3+ for Ba 2+ and Ce 4+ sites in BaCeO 3 and the ionic conduction[J].Solid State Ionics,1999,120:51-60.

[40]Takeuchi K,C.K,Loong.Richardson Jr J W,et al.The crystal structures and phase transitions in Y-doped BaCeO 3 :their dependence on Y concentration and hydrogen doping[J].Solid State Ionics,2000,138:63-77.

[41]Lei Bi,Zetian Tao,Wenping Sun,et al.Proton-conducting solid oxide fuel cells prepared by a single step co-firing process[J].Journal of Power Sources,2009,191:428-432.

[42]Kui Xie,Ruiqiang Yan,Xiaorui Chen,et al.A new stable BaCeO 3 -based proton conductor for intermediate-temperature solid oxide fuel cells [J] .Journal of Alloys and Compounds,2009,472:551-555.

[43]Lei Bi,Shangquan Zhang,Shumin Fang,et al.A novel anode supported BaCe 0.7 Ta 0.1 Y 0.2 O 3-δ electrolyte membrane for proton-conducting solid oxide fuel cell[J].Electrochemistry Communications,2008,10:1598-1601.

[44]Kui Xie,Ruiqiang Yan,Xingqin Liu.A novel anode supported BaCe 0.4 Zr 0.3 Sn 0.1 Y 0.2 O 3-δ electrolyte membrane for proton conducting solid oxide fuel cells[J].Electrochemistry Communications,2009,11:1618-1622.

[45]Masatsugu Oishi,Satoshi Akoshima,Keiji Yashiro,et al.Defect structure analysis of B-site doped perovskite-type proton conductingoxide BaCeO 3 Part 2:The electrical conductivity and diffusion coefficient of BaCe 0.9 Y 0.1 O 3-δ [J].Solid State Ionics,2008,179:2240-2247.

[46]Masatsugu Oishi,Satoshi Akoshima,Keiji Yashiro,et al.Defect structure analysis of B-site doped perovskite-type proton conducting oxide BaCeO 3 Part 1:The defect concentration of BaCe 0.9 M 0.1 O 3-δ (M=Y and Yb)[J].Solid State Ionics,2009,180:127-131.

[47]Zetian Tao,Zhiwen Zhu,Haiqian Wang,et al.A stable BaCeO 3 -based proton conductor for intermediate-temperature solid oxide fuel cells[J].Journal of Power Sources,2010,195:3481-3484.

[48]Chendong Zuo,Shaowu Zha,Meilin Liu,et al.Ba(Zr 0.1 Ce 0.7 Y 0.2 ) O 3-δ as an electrolyte for low-temperature solid-oxide fuel cells[J].Advanced Materials.2006,18,3318-3320.

[49]Lei Yang,Chendong Zuo,Shizhong Wang,et al.A novel composite cathode for low-temperature SOFCs based on oxide proton conductors[J].Advanced Materials.2008,20,3280-3283.

[50]Lei Yang,Chendong Zuo,Meilin Liu.High-performance anode-supported solid oxide fuel cells based on Ba(Zr 0.1 Ce 0.7 Y 0.2 )O 3-δ (BZCY)fabricated by a modified co-pressing process[J].Journal of Power Sources,2010,195:1845-1848.

[51]凌意瀚.基于固体氧化物燃料电池应用的基础研究[D].合肥:中国科学技术大学材料学材料学,2013.

[52]任铁梅.固体氧化物燃料电池及其材料[J].电池,1993,23(4):191-194.

[53]迟克彬,李方伟,李影辉,等.固体氧化物燃料电池研究进展[J].天然气工,2002,4(27):37-43.

[54]郭挺.固体氧化物燃料电池电解质和阳极材料的制备方法及性能研究[D].合肥:中国科学技术大学凝聚态物理,2014.

[55]周银,马桂君,刘红芹,等.固体氧化物燃料电池材料的研究进展[J].化工新型材料,2014,3(42):13-18.

[56]李中秋,侯桂芹,张文丽.钙钛矿型固体电解质材料的发展现状[J].河北理工学院学报,2006,1(28):71-73.

[57]程继海,王华林,鲍巍涛.钙钛矿结构固体电解质材料的研究进展[J].材料导报,2008,9(22):22-24.

[58]徐志弘,温廷琏.掺杂BaCeO 3 和SrCeO 3 在氧、氢及水气气氛下的电导性能[J].无机材料学报,1994,9(1):122-128.

[59]陈威,王常珍,刘亮.测熔融铝合金中氢活度的传感法研究[J].金属学报,1995,31(7):305-310.

[60]马桂林.Ba 0.95 Ce 0.90 Y 0.10 O 3-α 固体电解质的质子导电性[J].无机化学学报,1999,15(6):798-801.

[61]仇立干,马桂林.Ba 0.95 Ce 0.90 Y 0.10 O 3-α 固体电解质的氧离子导电性[J].无机化学学报,2000,16(6):978-982.

[62]马桂林,贾定先,马桂林.BaCe 0.9 Y 0.1 O 3-α 固体电解质燃料电池性能[J].化学学报,2000,58(11):1340-1344.

[63]张俊英,张中太.BaCeO 3 和SrCeO 3 基钙钛矿型固体电解质[J].北京科技大学学报,2000,22(3):249-252.

[64]马桂林,仇立干,贾定先,等.BaCe 0.8 Y 0.2 O 3-α 固体电解质的离子导电性及其燃料电池性能[J].无机化学学报,2001,17(6):853-858.

[65]陶宁,蒋凯.固体电解质BaCe 1-x RE x O 3-δ 的电导率及燃料电池性能[J].合肥工业大学学报(自然科学版),2001,24(5):959-962.

[66]陈蓉,马桂林,李宝宗.Ba 1.03 Ce 0.8 Dy 0.2 O 3-α 固体电解质的合成及其离子导电性[J].无机化学学报,2002,18(12):1200-1204.

[67]仇立干,马桂林.Ba x Ce 0.8 Y 0.2 O 3-α 固体电解质的氧离子导电性[J].无机化学学报,2003,19(6):665-668.

[68]李朝辉,连建设,刘喜明.中温陶瓷燃料电池电解质与电极材料研究现状[J].长春工业大学学报,2003,24(3):24-27.

[69]马桂林,仇立干,陶为华,等.Ba x Ce 0.8 Sm 0.2 O 3-α 固体电解质的离子导电性[J].中国稀土学报,2003,21(2):236-240.

[70]梅辉,冯丽萍,费敬银.氢传感器材料前驱粉体的低温制备[J] .腐蚀与防护,2004,25(6):252-255.

[71]陈蓉,马桂林.Ba 1.03 Ce 0.8 Gd 0.2 O 3-α 固体电解质的合成及其燃料电池性能[J].苏州大学学报(自然科学版),2006,22(4):74-76.

[72]王记江,李东升,胡怀明,等.BaCeO 3 基高温质子导体研究进展[J].延安大学学报(自然科学版),2006,25(4):59-64.

[73]李雪,赵海雷,张俊霞,等.SOFC用钙钛矿型质子传导固体电解质[J].电池,2007,37(4):303-305.

[74]王东,范建华,刘春明,等.BaCe 1-x Y x O 3-α 及BaCe 0 .9 Sm 0 .1 O 3-α 质子导体的表征及组成氢泵对铝熔体的脱氢[J].金属学报,2007,43(11):1228-1232.

[75]王金霞,姚瑛,苏树兵,等.BaCe 0.75 Y 0.23 O 3-δ 中温电解质的制备及单电池性能[J].吉林大学学报(理学版),2007,45(6):1000-1002.

[76]杨晓蓉,孙凡.BaCe 0.8 M 0.2 O 29 (M=Y、Gd、Sm)电解质在中、低温天然气燃料电池中的性能研究[J].新疆师范大学学报(自然科学版),2008,27(3):65-69.

[77]王东,刘春明,王常珍.高温质子导体BaCe 0.90 Y 0.10 O 3-α 的制备与性质[J].材料与冶金学报,2008,7(4):273-279.

[78]王茂元,仇立干,马桂林.BaCe 0.7 Zr 0.2 La 0.1 O 3-α 陶瓷的制备和导电性[J].无机化学学报,2008,24(3):357-362.

[79]谭文轶,钟秦,曲虹霞.采用固体氧化物燃料电池反应器脱除H 2 S[J].化工环保,2009,29(1):23-25.

[80]王茂元,仇立干,左玉香.BaCe 0.5 Zr 0.4 La 0.1 O 3-α 陶瓷的制备及其电性能[J].化学学报,2009,67(12):1349-1354.

[81]刘进伟,李亚东,王文宝,等.BaCe 0.9 Ca 0.1 O 3-α 的溶胶凝胶法合成及中温质子导电性[J].苏州大学学报(自然科学版),2010,26(2):79-83.

[82]仇立干,王茂元.非化学计量组成Ba 1.03 Ce 0.5 Zr 0.4 La 0.1 O 3-α 的化学稳定性和离子导电性[J].化学学报,2010,68(3):276-282.

[83]刘魁,戴磊,唐晓微,等.Ti和Y双掺杂的BaCeO 3 的制备和电性能研究[J].功能材料,2010,41(1):51-54.

[84]杨晓龙,夏春谷,熊绪茂等.铈酸钡和钇掺杂的铈酸钡复合氧化物的制备及其在钌基氨合成催化剂中的应用[J].催化学报,2010,31(4):377-379.

[85]王茂元,仇立干.BaCe 0.8 Zr 0.1 La 0.1 O 3-α 陶瓷的制备和电性能研究[J].化学研究与应用,2011,23(8):1051-1056.

[86]邹文斌,朱俊武,杨绪杰,等.甘氨酸-硝酸盐燃烧法合成BaCeO 3 纳米粉末[J].南京理工大学学报,2011,35(4):563-566.

[87]江虹,郭瑞松,徐江海,等.氧化钇掺杂锆铈酸钡质子导体的制备及性能研究[J].无机材料学报,2012,27(12):1256-1260.

[88]韩丹丹,路大勇.单相BaCeO 3 陶瓷的制备研究[J].吉林化工学院学报,2012,29(5):87-91.

[89]蒋红旺,赵鸿宇,段迎文.Sol-gel法制备铈酸钡纳米粉末[J].材料导报,2012,26(20):72-74.

[90]王茂元,仇立干,孙玉凤.Ba 0.9 Sr 0.1 Ce 0.9 Nd 0.1 O 3-α 陶瓷的离子导电性[J].无机化学学报,2012,28(2):285-290.

[91]韩伟,余唐琪,魏勤,等.BaCe 0.7 Zr 0.1 Y 0.2 O 3-δ 的合成、电学性能和化学稳定性[J].新疆师范大学学报(自然科学版),2014,33(3):26-32.

[92]江虹,郭瑞松,李永,等.Y和Yb复合掺杂对BaCe 0.5 Zr 0.3 Y 0.2-x Yb x O 3-δ 的烧结性和电导率的影响[J].硅酸盐通报,2014,33(3):515-519.

[93]王静任,刘宏光,彭开萍.固相反应对钆掺杂二氧化铈和钇掺杂铈酸钡电解质电化学性能的影响[J].硅酸盐学报,2015,43(2):189-194. fEpeIEvVgKMEqTUD120vV4DZ9kNdffVc1+n/m2BM91iPBVPIrUdTf/x+nWM66l2g

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